Alkylation of resorcinol with tertiary butanol over zeolite catalysts: Shape selectivity vs acidity

Shape Selective Alkylation of Biphenyl with 1-octene on ((Al+C3H7Cl)+C2H4) Catalysts

Alkylation of biphenyl with 1-octene was investigated using ((Al+C3H7Cl)+C2H4) catalysts. The catalytic activity of ((Al+C3H7Cl)+C2H4) for the alkylation was studied at different temperatures, mol ratios of biphenyl to 1-octene, reaction times and catalyst concentrations. It was shown that using this catalyst has more advantagous than another catalysts. Experiments show that by increasing t...

Morphology Induced Shape Selectivity in Zeolite Catalysis

Understanding zeolite catalysis: inverse shape selectivity revised.

Anyone who has experience in moving house [the Angewandte team has just done this!] knows that those boxes filled with small books are the heaviest, because these small objects pack so easily. The same entropy effect explains the catalytic selectivity towards the formation of branched hydrocarbons in zeolites. The pink tubes represent the zeolite pores at high loading in which effective size di...

Isobutane/2-Butene Alkylation with Zeolite Y without Br∅nsted Acidity

Foi estudada a alquilação de isobutano com 2-buteno catalisada por zeólitas Y trocadas com cátions metálicos, usando um cloreto de alquila com iniciador de carbocátions. Os resultados indicaram que, comparavelmente a uma zeólita protônica, a desativação foi significativamente mais lenta e a produção de tri-metilpentanos foi maior nas zeólitas trocadas com metais. Os cátions agem como sítios áci...

shape selective alkylation of biphenyl with 1-octene on ((al+c3h7cl)+c2h4) catalysts

alkylation of biphenyl with 1-octene was investigated using ((al+c3h7cl)+c2h4) catalysts. the catalytic activity of ((al+c3h7cl)+c2h4) for the alkylation was studied at different temperatures, mol ratios of biphenyl to 1-octene, reaction times and catalyst concentrations. it was shown that using this catalyst has more advantagous than another catalysts. experiments show that by increasing tempe...